Textbook models will need to be re-drawn after a team of researchers found that water molecules at the surface of salt water are organized differently than previously thought.
Many important reactions related to climate and environmental processes take place where water molecules interface with air. For example, the evaporation of ocean water plays an important role in atmospheric chemistry and climate science. Understanding these reactions is crucial to efforts to mitigate the human effect on our planet.
The distribution of ions at the interface of air and water can affect atmospheric processes. However, a precise understanding of the microscopic reactions at these important interfaces has so far been intensely debated.
In a paper published in the journal Nature Chemistry, researchers from the University of Cambridge and the Max Planck Institute for Polymer Research in Germany show that ions and water molecules at the surface of most salt-water solutions, known as electrolyte solutions, are organized in a completely different way than traditionally understood. This could lead to better atmospheric chemistry models and other applications.
Kind of interesting
“Our work demonstrates that the surface of simple electrolyte solutions has a different ion distribution than previously thought and that the ion-enriched subsurface determines how the interface is organized: at the very top there are a few layers of pure water, then an ion-rich layer, then finally the bulk salt solution.”